Adsorption

SubμTrack

KALEH — Tue, 19 Dec 2017 15:21:00 +0000

SubμTrack KALEH Tue, 12/19/2017 - 16:21

Tracking of (Sub)Microplastics of Different Identities - Innovative Analysis Tools for Toxicological and Process-engineering Evaluation

The methods currently available for the analysis of microplastics in environmental matrices were primarily designed for particles in the size range of 1 μm to 5 mm. Smaller particles below 1 μm were hardly detected. However in contrast to larger particles, these are able to enter cells and have a higher potential for adsorption of pollutants due to their relatively larger surface. SubμTrack focuses on plastic particles between 50 nm and 100 μm, because of their higher ecotoxicological relevance. For this purpose, the previously available detection range was extended and new methods for sampling, sample preparation, and analysis were developed. Another focus of the project were the possible effects of submicroplastic particles on the aquatic environment and on human health. The results of these studies were complemented by an assessment of the social, political and legal dimensions of plastic emission into the environment. By analysing the perception of the problem and possible strategies for action, foundations were laid for active processes of social change. The results were also examined regarding to their implementation in legislation, standardisation, and their relevance for voluntary actions.

Main areas of work

Characterisation of particles and comparison with reference materials
Impact on the aquatic environment and human health
Social, political and legal dimensions of plastic emission into the environment

Arbeitspakete

Work packages

WP 0 Organisation, coordination and public relations

Contact persons
Prof. Dr.-Ing. Jörg E. Drewes, Technical University of Munich, Chair of Urban Water Systems Engineering, Am Coulombwall 3, 85748 Garching, e-mail: j.drewes@tum.de

Project partner
TUM-IWC, TUM-LTI, TUM-LAS, TUM-MCTS, IGOE, LfU, UBA, IUTA, Postnova Analytics GmbH, BS-Partikel GmbH

Short description
In addition to the coordination of results and products within the consortium, WP 0 also included the coordination of activities with partners outside the project. The goal was the sustainable implementation of the analytical techniques, the results and the instructions for action of harmonised strategies in close cooperation with national and international key institutions. The public relations work was mainly coordinated by TUM-SWW and effectively implemented by partners of different orientations.

WP 1 Selection and production of reference particles

Contact persons
Dr. Carmen Nickel, Dr. Jochen Türk, Institute of Energy and Environmental Technology e. V. (IUTA), Bliersheimer Str. 58- 60, 47229 Duisburg, e-mail: nickel@iuta.de; tuerk@iuta.de

Project partner
LfU, BS-Partikel GmbH

Short description
Together with the partners of BS-Partikel and the leaders of the experimental WPs 2 – 5 the required reference particles were identified. In particular, the size, material, marking and the availability of the particles played an important role. The reference particles were selected during the initial phase of the project in order to have enough time to fabricate or purchase the particles at the beginning of the experiments. The project partners BS-Partikel and IUTA then provided the corresponding particles.

WP 2 Comprehensive analysis of microplastic particles

Contact persons
Prof. Dr. Martin Elsner, Dr. Natalia P. Ivleva, Technical University of Munich, Chair of Analytical Chemistry and Water Chemistry, Institute of Hydrochemistry, Marchionistrasse 17, 81377 Munich, e-mail: natalia.ivleva@ch.tum.de

Project partner
Postnova Analytics GmbH, BS-Partikel GmbH, TUMSWW, TUM-LTI, LfU, IUTA

Short description
Innovative and proven analytical detection methods (including sampling, preparation, identification and quantification) for microplastics (1 μm – 5 mm) were determined and tested with reference materials in the submicron range. The most successful techniques of the MiWa project running since 2016 serve as a starting point for this; standard methods from this project were integrated and compared. Direct contact to actors of the MiWa project was guaranteed by partners of the consortium (TUM-IWC and UBA).

WP 3 Studies on aging, adsorption and desorption of organic trace substances on reference particles

Contact persons
Prof. Dr.-Ing. Jörg E. Drewes, Technische Universität München, Lehrstuhl für Siedlungswasserwirtschaft, Am Coulombwall 3, 85748 Garching, e-mail: j.drewes@tum.de

Project partner
LfU

Short description
The particles used in the method validation are subjected to systematic aging processes and biofilm growth. Furthermore, these particles and especially their (resulting) different surfaces were examined regarding their adsorption or desorption characteristics of organic molecules. For this analysis, adsorption and desorption kinetics, among other things, were investigated. This was done by applying TD-(Pyrolysis)-GC-MS and LC-MS/MS. Experiments with the aged particles were carried out in so-called batch approaches, but also in laboratory wastewater treatment plants operated at the LfU. All samples were also stored in the biological systems of WP 5 if required.

WP 4 Investigations on entry points and process-related evaluation

Contact person
Dr. Korbinian Freier, Bavarian State Office for the Environment, Demollstraße 31, 82407 Wielenbach, e-mail:korbinian.freier@lfu.bayern.de

Project partner
TUM-SWW, IUTA

Short description
Using the methods developed and validated in WP 2, real scenarios were first simulated with reference particles in laboratory wastewater treatment plants at the partner LfU to analyse the fate of the particles within the system. Parallel to this, investigations were carried out at various measuring points in real wastewater treatment plants. Water samples were certified by IUTA for micropollutants. The aim was to extend the existing sampling technologies to micropollutants. Finally, together with the other partners of the project and based on the expected results, a process-related evaluation was carried out.

WP 5 Impact on aquatic environment and human health

Contact person
Prof. Dr. Michael Pfaffl, Technical University of Munich, TUM School of Life Sciences Weihenstephan, Technical University of Munich, Chair of Animal Physiology and Immunology, Weihenstephaner Berg 3, 85354 Freising, e-mail: michael.pfaffl@wzw.tum.de

Project partner
TAM-LAS, IGOE

Short description
Potential negative effects of submicroparticles on different biological organisational levels were investigated and compared to obtain a comprehensive ecotoxicological evaluation. This includes the use of model systems in vivo to determine effects on microbial diversity, communities and trophic structures and functions as well as to identify stress reactions on a higher organismic level. In vitro models extended this approach for the determination of effects on the cellular and molecular level. Based on this a mechanistic understanding of particle-induced stress reactions was created and potential effects on human health were derived.

WP 6 Social, political and legal dimensions

Contact person
Prof. Dr. Ruth Müller, Technical University of Munich, Assistant Professorship of Science and Technology Policy, Augustenstraße 46, 80333 Munich, e-mail: ruth.mueller@tum.de

Project partner
UBA

Short description
At TUM-MCTS current problem perceptions and coping strategies in society and politics with regard to plastic particles in the environment were analysed by means of qualitative social scientific methods. The focus lay on the perception of the specific ecotoxicological relevance of submicroparticles. UBA carried out a screening of the relevant legal acts at national, European and intercontinental levels. The consideration goes beyond the pure media reference (water, soil and air) and the associated possible transport paths. In particular, the legally undefined range between nano- (limit: 100 nm) and microplastics (frequently stated limit: 1 μm) is of primary interest.

Coordinator

Prof. Dr.-Ing. Jörg E. Drewes
Technical University of Munich,
Chair of Urban Water Systems Engineering / TUM-SWW
Am Coulombwall 3
85748 Garching
Phone: +49 89 2891 3701 bzw. -3718
e-mail: jdrewes@tum.de

Website

https://www.wasser.tum.de/en/ submuetrack/startseite/

Partner Institutions

Technical University of Munich

Institute of Hydrochemistry, Chair of Analytical Chemistry and Water Chemistry / TUM-IWC

Chair of Animal Physiology and Immunology/ TUM-LTI

Chair of Aquatic Systems Biology / TUM-LAS

Assistant Professorship of Science and Technology Policy / TUM-MCTS

Helmholtz Centre Munich, Institute of Groundwater Ecology / IGOE

Bavarian State Office for the Environment / LfU

Federal Environmental Agency / UBA

Institute of Energy and Environmental Technology e. V. / IUTA

Postnova Analytics GmbH

BS-Partikel GmbH

Duration Period

September 2017

June 2021

PLASTRAT

KALEH — Tue, 19 Dec 2017 14:34:18 +0000

PLASTRAT KALEH Tue, 12/19/2017 - 15:34

Strategies for Reducing the Entry of Urban Plastics into Limnic Systems

The common element of all investigations in PLASTRAT was the development of solution strategies for sustainable limitation of the spread of plastic residues in the aquatic environment on technical, environmental, scientific and social-ecological levels. The objective consisted of developing a multi-criteria evaluation approach for the environmental compatibility of different types of plastics. In addition, a quality label for practical application was designed. The focus lay on the analysis and evaluation of the degradation stages of different types of plastics as well as leaching, adsorption and desorption in different wastewater treatment stages, the effects of different plastic species (in different degradation stages) and their additives on aquatic organisms in limnic systems, as well as a risk characterisation of the human toxicological effect of microplastics on consumers of drinking water. Furthermore, the emphasis is put on the quantification and technical reduction potential (e.g. use of membrane technology) of plastic emissions in urban water management, including sewage sludge/fermentation residue treatment, taking into account suitable sampling, treatment and analysis methods. Besides, studies were carried out on the social relevance, i.e. how plastics are handled in German households, what demands the consumer places on plastics, what possibilities exist for the use of substitutes and the resulting effects on commerce, logistics and consumers.

Main areas of work

Determination and evaluation of microplastic pathways in limnic systems
Investigation and evaluation of technical measures for microplastic elimination
Sampling strategies for further processing and analysis of microplastics
Sample preparation for analysis of microplastics
Identification and quantification of microplastics in all samples
Automation of particle recognition, measurement and identification using databases
Adsorption/desorption of pollutants on microplastics
Degradation and leaching of polymers of different groups
Ecotoxicological studies of released substances from microplastics
Human toxicological investigations of released substances from microplastics
Risk analysis of drinking water
Investigation of societal relevance
Development of a multi-criteria evaluation system
Development of a quality label through an accompanying stakeholder dialogue

Arbeitspakete

Work packages

WP K Coordination und Communikation

Contact persons
Prof. Dr.-Ing. Christian Schaum, apl. Prof. Dr.-Ing. Steffen Krause, Bundeswehr University Munich, Institute of Hydroscience, Chair of Sanitary Engineering and Waste Management, Werner-Heisenberg-Weg 39, 85577 Neubiberg, e-mail: swa@unibw.de

Short description
In addition to the tasks of general scientific project management, internal communication between the network partners and external communication (increasing public awareness of the project) were also covered. This includes, among other things, uniform guidelines for public relations work by individual network partners and within the overall consortium, organisation of meetings, monitoring of work progress, document management and coordination of the associated partners.

WP 1 Microplastics in the urban water cycle

Project partner
UF, IWW, BfG, a2i, TUDa, inge, IPF, IOW

Short description
Basic data and definitions for PLASTRAT were specified in consultation with all project partners. This relates to the definition of the upper and lower limit of the particle size for microplastic particles to be examined, the selection of specific plastic species from the categories conventional plastics, recyclates, and biobased or biodegradable polymers. Further work included the selection or determination of suitable sites for investigations of WP 2 and 3, taking into account the products considered in WP 5. In addition, a stakeholder analysis was carried out along with a more detailed evaluation for developing the quality label.

WP 2 Degradation und material dynamics

Contact person
Prof. Dr. Thomas Ternes, German Federal Institute of Hydrology (BfG), Am Mainzer Tor 1, 56068 Koblenz, e-mail: ternes@bafg.de

Project partner
UniBwM, TUDa

Short description
The environmental behaviour of biobased, synthetic and recycled plastics was analysed in WP 2. Original materials were examined, as well as artificially-aged materials. The release of pollutants (oligomers, additives and their transformation products) was analysed depending on the type of polymer and the degree of degradation. Furthermore, differences in the adsorption/desorption of environmental chemicals were investigated for different types of polymers and the role of wastewater treatment plants regarding the pollutant load of microplastics (enrichment or depletion).

WP 3 Entry points and elimination

Project partner
UniBwM, a2i, inge, IPF, IOW

Short description
Different entry points of microplastics into limnic systems were assessed, focusing on the analysis and evaluation of the waste water management system including measures for microplastic retention (e.g. membrane technology) that already exist or have been modified or developed in the course of the project. Core areas comprised rain and mixed water discharge, the assessment and evaluation of the entire wastewater treatment plant system, and an analysis of sewage sludge, digestate and compost as possible microplastic sinks. Emphasis was also put on the development and selection of suitable processing and analytical methods.

WP 4 Impact and hazard analysis

Contact persons
Prof. Dr. Jörg Oehlmann, Dr. Ulrike Schulte-Oehlmann, Goethe University Frankfurt, Max-von-Laue-Straße 13, 60438 Frankfurt, e-mail: oehlmann@bio.uni-frankfurt.de

Project partner
IWW

Short description
Comparative analyses were conducted for biobased, synthetic and recycled plastics in different degradation stages as well as for their additives and substances adsorbed/desorbed regarding their effects applying various human and ecotoxicological methods. The results were used to derive threshold values and environmental quality objectives. These contributed to the hazard analysis and evaluation of the different plastic species with regard to their relevance and environmental compatibility for the limnic environment. The experimental investigations were supplemented by a risk analysis of the drinking water system.

WP 5 Societal relevance

Contact person
Dr. Immanuel Stieß, ISOE - Institute for Social-Ecological Research, Hamburger Allee 4, 60486 Frankfurt, e-mail: stiess@isoe.de

Short description
The social perception, use and disposal of plastic based products were analysed as well as the possibilities, conditions and obstacles for more sustainable consumption and disposal practices. The focus lay on applications in the non-food sector (hygiene articles, clothing and dog excrement bags) as their incorrect or informal disposal can lead to the emission of microplastics into limnic systems that may have negative effects on organisms and aquatic ecosystems. Analysing of the perception of environmental risks and product-specific use and disposal practices was carried out through qualitative exploration and standardised surveys.

WP 6 Evaluation system/quality label

Contact person
Kristina Wencki, IWW Rheinisch-Westfälisches Institute for Water Research gGmbH, Moritzstraße 26, 45476 Mülheim an der Ruhr, e-mail: k.wencki@iww-online.de

Project partner
ISOE, UniBwM, UF, BfG

Short description
Within the project, a multi-criteria evaluation system for plastics regarding to their environmental compatibility with limnic systems was developed. At the same time, the identification of the evaluation criteria was used to initiate the critical discourse about the quality label that demonstrates this environmental compatibility. To this end, a stakeholder dialogue was conducted. In addition to synthesizing the outcomes of the preceding work packages, this made a significant contribution to transfer the newly acquired findings into research and business practice.

Coordinator

Prof. Dr.-Ing. Christian Schaum and apl. Prof. Dr.-Ing. Steffen Krause
Bundeswehr University Munich Institute of Hydroscience /
UniBwM Chair of Sanitary Engineering and Waste Management
Werner-Heisenberg-Weg 39
85577 Neubiberg
Phone: + 49 89-6004-2061 bzw. -2698 /-3849
e-mail: swa@unibw.de

Website

http://www.plastrat.de/project/

Partner Institutions

Goethe University Frankfurt / UF

Institute for Social-Ecological Research/ISOE

IWW Rheinisch-Westfälisches Institute for Water Research gGmbH / IWW

German Federal Institute of Hydrology (BfG) / BfG

aquadrat ingenieure GmbH / a2i

Technical University of Darmstadt, Institute IWAR /TUDa

inge GmbH /inge

Leibniz Institute of Polymer Research Dresden / IPF

Leibniz Institute for Baltic Sea Research Warnemünde / IOW