Raman spectroscopy

Analytics

Sampling

Soil

Cross-Cutting Topic 1: Analytics and Reference Materials: Comparative test

Publikationstyp

QST1: Vergleichsversuch

janna.vakili@ecologic.eu — Fri, 12 Feb 2021 09:52:50 +0000

Cross-Cutting Topic 1: Analytics and Reference Materials: Comparative test janna.vakili@e… Fri, 02/12/2021 - 10:52

Untertitel

Results

Titelbild

Beschreibung

This comparative test from cross-cutting topic 1 "Analytics and reference materials" classifies different analytical methods for the identification and quantification of microplastics regarding their informative value and to work out the strengths and limitations of the respective methods. The comparative test was intended to provide the pre-requisites for comparing the analytical results of the individual projects within a given framework. No evaluation of the different analytical methods is intended.

Both thermoanalytical and spectroscopic methods were used. It was shown that the different analytical methods for the identification and quantification of microplastics provide comparable results within the respective procedures.

The results of the comparative test are available here as a PDF download.

Attachments

Year

2021

Author

Authors

PD Dr. Natalia Ivleva

Prof. Dr. rer. nat. Heinz Sturm

Cordula Witzig

Dr. Nicole Zumbülte

Type of Result

discussion papers & status papers

Tags

Polymer

Polymer analysis

https://www.io-warnemuende.de/microcatch-home.html

Publikationstyp

MicroCatch_Balt

KALEH — Wed, 20 Dec 2017 09:57:04 +0000

MicroCatch_Balt KALEH Wed, 12/20/2017 - 10:57

Investigation of Sinks and Sources of Microplastics from a Typical Catchment Area to the Open Baltic Sea

This project determined sources and sinks of microplastic in the Warnow river basin, as well as relevant dissemination processes on its way to the open Baltic Sea. Separate models were linked so that the resulting model covers the entire river basin including estuary and coastal waters. The linked models served to identify hotspot areas of microplastic entry and to estimate the effects of microplastic reduction measures in parts of the river basin. By converting the models into a handson multitouch table, project participants made interactive, creative learning modules that were presented in the form of a traveling exhibition in communities around the German Baltic coast from Stralsund to Flensburg. Further, MicroCatch_Balt included the examination of anti-fouling paint and extreme weather events as sources and higher organisms as sinks. Based on this, MicroCatch_Balt covered the most important aspects of microplastic contamination of limnic to marine systems in northern Germany, thereby offering interest groups the expertise with which to develop future monitoring and strategies for reduction.

Main areas of work

Sampling in the Warnow river basin and estuary, extraction and identification of microplastics
Modelling of microplastic input into the Warnow system of diffuse and point sources
Development of two multi-media modules for a multi-touch table and organisation of a traveling exhibition

Arbeitspakete

Work packages

WP 1 Sampling of microplastic from the environment

Contact person
PD Dr. habil. Matthias Labrenz, Leibniz Institute for Baltic Sea Research, Environmental Microbiology, Seestraße 15, 18119 Rostock, e-mail: matthias.labrenz@io-warnemuende.de

Project partner
IPF

Short description
In WP 1, environmental samples (water, sediment, soil, benthic and pelagic higher organisms) were collected, processed and identified in the Warnow area. Of particular interest were potential sources such as wastewater treatment plants / sewage separation, drainage ditches, erosion areas, industrially influenced areas as well as extreme events like Hanse Sail, New Year‘s Eve, heavy rain and storm events. Potential sinks, including higher organisms (mussels, worms, fish), beaches and sediments were also sampled. In all samples, the microplastic particles were identified and quantified using spectroscopic methods.

WP 2 Modelling of the Warnow estuary and the catchment area

Contact person
Dipl.-Ing.agr. Peter Kreins, Johann Heinrich von Thünen Institute - Federal Research Institute for Rural Areas, Forestry and Fisheries, Bundesallee 50, 38116 Braunschweig, e-mail: peter.kreins@thuenen.de

Project partner
FZJ, IOW

Short description
By adapting and combining different regional models, spatially high-resolution modelling of landside diffuse and point source of microplastic emissions into the river basin of the Warnow took place. In this way, on the one hand the hotspots of pollution in the Warnow river area were identified and on the other hand the entire landside microplastic entries into coastal waters were quantified.

WP 3 Microplastics Touring Exhibition

Contact person
Dr. Barbara Hentzsch, Leibniz Institute for Baltic Sea Research Warnemünde, Scientific Management and Communication, Seestraße 15, 18119 Rostock, e-mail: barbara.hentzsch@io-warnemuende.de

Project partner
FhIGD

Short description
In WP 3 a traveling exhibition with an interactive multimedia learning module was developed, which presents the project results in the form of animations. The traveling exhibition was shown in Stralsund, Rostock, Hamburg, Kiel, Eckernförde and Flensburg. The respective exhibition openings was accompanied by plenary discussions with representatives of the local environmental authorities and scientists.

WP 4 Project management

Contact person
PD Dr. habil. Matthias Labrenz, Leibniz Institute for Baltic Sea Research, Environmental Microbiology, Seestraße 15, 18119 Rostock, e-mail: matthias.labrenz@io-warnemuende.de

Short description
WP 4 covered project management and ensured efficient and productive execution of the project. The tasks of WP 4 included coordination with the other “Plastics in the Environment” projects PLAWES, PLASTRAT and the BONUS project MICROPOLL, as well as monitoring finances and work results, organising regular project meetings, disseminating project results to the public, and supporting the project manager with regard to internal and external scientific communication.

Coordinator

PD Dr. habil. Matthias Labrenz
Leibniz Institute for Baltic Sea Research Warnemünde / IOW,
Environmental Microbiology
Seestraße 15
18119 Rostock
Phone: +49 381/5197378
e-mail:matthias.labrenz@io-warnemuende.de

Website

Partner Institutions

Leibniz Institute of Polymer Research Dresden / IPF

Jülich Research Centre, Institute for Bio- and Geosciences / FZJ-IBG

Johann Heinrich von Thünen Institute - Federal Research Institute for Rural Areas, Forestry and Fisheries / TI-LR

Fraunhofer Institute for Computer Graphics Research IGD Rostock / FhIGD

Duration Period

August 2017

April 2021

Tags

Information and teaching materials

19_Projektblatt_MicroCatchBalt_ENG_2018.pdf

Combined sewar overflows

Project sheet

Koordinator label

http://www.bayceer.uni-bayreuth.de/PLAWES/en/

PLAWES

KALEH — Wed, 20 Dec 2017 09:29:04 +0000

PLAWES KALEH Wed, 12/20/2017 - 10:29

Microplastic Contamination in the Weser- Wadden Sea – National Park Model System: an Ecosystem-Wide Approach

In PLAWES, the modelling system of the German national park Weser-Wadden Sea was the first large European river basin that was investigated in detail regarding its microplastic pollution. PLAWES conducted a pioneering study of the microplastic contamination from the headwaters to the North Sea (northern Atlantic Ocean) that comprised an interdisciplinary and integrated ecosystem approach and accounted for various point sources (wastewater treatment plants, separation systems) and diffuse sources (drainage, atmosphere) of pollution. The results were integrated into a model for identifying primary transport mechanisms and accumulation zones. The research investigated the effects of microplastics on ecosystems in the Weser-Wadden Sea system by analysing the interaction of microplastic with pathogens in biofilm and aquatic invertebrates. Outcomes of this particularly ecologically relevant aspects were used to estimate the environmental risk of microplastics for the model system, and subsequently made it transferable to other systems. In addition, the results of the analysis became part of new teaching materials in order to provide a knowledge platform for teachers, students, and parents across Europe. PLAWES generated unique data about the effects of microplastics on a large European river basin and its environment. This is significant not only for policymakers and stakeholders but also as a fundament for science-based solutions to address the microplastics problem.

Main areas of work

Microplastics in the Weser-Wadden Sea
Model-based balancing of diffuse and point sources of microplastic entries
Interaction of microplastics with pathogens and biota
Training measures to raise awareness of plastic waste

Arbeitspakete

Work packages

WP 0 Management, communication and dissemination

Contact person
Prof. Dr. Christian Laforsch, University of Bayreuth, Universitätsstraße 30, 95447 Bayreuth, e-mail: christian.laforsch@uni-bayreuth.de

Project partner
AWI

Short description
WP 0 ensured the targeted and efficient support of the consortium with regard to project management, communication and dissemination. WP 0 coordinated both the public relations work and the exploitation of the results achieved. WP 0 continued to coordinate the cooperation of all project partners and was therefore in close contact with all project partners. WP 0 coordinated the harmonisation with the joint research project MicroCatch_Balt with regard to sampling and processing, modelling, public relations, and data storage as well as communication with the other projects.

WP 1 Microplastics in the Weser-Wadden Sea model system

Contact person
Dr. Gunnar Gerdts, Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research, Kurpromenade, 27498 Helgoland, e-mail: gunnar.gerdts@awi.de

Project partner
UBT, UOld

Short description
The aim of WP 1 was to investigate the entire Weser river system into coastal waters with regard to microplastic pollution. The final determination of the exact sampling points was carried out taking into account the real data required for RAUMISmGROWA- MePhos and "Tidal Model" (WP 3). The entire Weser including the Lower Weser and the Wadden Sea was investigated with regard to exposure to microplastic. Two campaigns were carried out at different seasons with different water conditions on the Weser.

WP 2 Entry points – point sources and diffuse entry

Contact person
Prof. Dr. Andreas Held, University of Bayreuth, BayCEER; second affiliation: Technical University of Berlin, Department of Environmental Chemistry and Air Pollution Control, Straße des 17. Juni 135, 10623 Berlin, e-mail: held@tu-berlin.de

Project partner
AWI

Short description
The aim of WP 2 was an exemplary consideration of the input paths for microplastics by investigation of important point sources such as wastewater treatment plants and separation water sewer systems as well as the diffuse input from drains and atmosphere. For this purpose, selected sampling points in the Weser river basin were characterised taking into account different landscape areas and land use types. The focus lay on quantifying the entry points of microplastics. Sampling was synchronised with the campaigns at the Weser.

WP 3 Model-based accounting of diffuse and point-shaped MP entries

Contact person
Prof. Dr. Frank Wendland, Jülich Research Centre IBG-3, Wilhelm-Johnen-Straße, 52428 Jülich, e-mail: f.wendland@fz-juelich.de

Project partner
TI, NLWKN

Short description
The aim was a spatially resolved quantification of the microplastic emissions from diffuse and point sources and the identification of spatial load centres and accumulation zones within the river basin and estuary. The microplastic entries were modelled from different types of diffuse entry points and point sources. The work was based on the models mGROWA, MEPhos, RAUMIS, as well as a transport modelling considering the estuarine hydro- and sediment dynamics. Within the framework of the project, the model chain was improved in a targeted manner according to microplastic entry modelling in the inland and the further distribution of the microplastics in the lower reaches, estuary and apron.

WP 4 Interaction of microplastic with pathogens and biota

Contact person
Prof. Dr. Jörg Oehlmann, Goethe University Frankfurt, Max-von-Laue-Straße 13, 60438 Frankfurt am Main, e-mail: oehlmann@bio.uni-frankfurt.de

Project partner
AWI, UBT, UOld

Short description
In WP 4, the ecosystem effects of microplastic on the Weser-Wadden Sea model system were described on the basis of the two ecologically relevant aspects "Interaction with pathogens and antimicrobial resistance" and "Interaction with aquatic invertebrates".

Interaction with pathogens and antimicrobial resistance: Since biofilms are sites of increased genetic exchange and increased antimicrobial resistance occurs below wastewater treatment plants, plastics could not only contribute to the dispersion of pathogenic organisms, but also of resistance genes. The consequences of such a transfer were previously unknown. AWI therefore used molecular microbial source tracking techniques (DNA/RNA arrays for the detection of pathogenic bacteria, viruses, protozoa and virulence/resistance genes) to investigate plastic samples from the Weser region. Interaction with aquatic invertebrates: In order to generate exposure data, different mollusk species were applied in situ in the Weser, the tidal area and the Wadden Sea. Absorbed microplastic was examined in the digestive tract and in tissue samples and confirmed in parallel by pyrolysis-GC-MS and spectroscopic methods. Historical mussel samples (since 1986) from the Federal Environmental Specimen Bank (UBA) were examined using pyrolysis-GC-MS. The chronic toxicity of microplastic is characterised in laboratory experiments with mussels and worms. Different polymers were conditioned in situ and toxicologically characterised in chronic exposure experiments.

WP 5 Training measures to raise awareness of plastic waste

Contact person
Prof. Dr. Franz X. Bogner, University of Bayreuth, Didactics of Biology, Universitätsstraße 30, 95447 Bayreuth, e-mail: franz.bogner@uni-bayreuth.de

Project partner
AWI, UOld

Short description
In addition to the ethical assessment skills of students, WP 5 incorporated existing individual environmental knowledge. Innovative teaching materials with a sound reference to everyday life were evaluated for a holistic understanding regarding the burden of plastics in the model system and disseminated via an Internet teaching/learning portal. Within the work package, UBT provided a handbook for teachers and "public relations workers".

Coordinator

Prof. Dr. Christian Laforsch
University of Bayreuth
Chair of Animal Ecology I / UBT
Universitätsstraße 30
95447 Bayreuth
Phone: +49 921 / 55-2651
e-mail: christian.laforsch@uni-bayreuth.de

Dr. Gunnar Gerdts
Alfred Wegener Institute
Helmholtz Centre for Polar and Marine Research (AWI)
Kurpromenade
27498 Helgoland
Phone: +49 4725 / 819-3245
e-mail: gunnar.gerdts@awi.de

Website

Partner Institutions

Coast Research Centre at the Lower Saxony State Enterprise for Water Management, Coastal Protection and Nature Conservation / NLWKN

Jülich Research Centre / FZJ

Goethe University Frankfurt / GU

Johann Heinrich von Thünen Institute - Federal Research Institute for Rural Areas, Forestry and Fisheries / TI-LR

Carl von Ossietzky University of Oldenburg, Institute of Chemistry and Biology of the Sea / UOld

Duration Period

September 2017

April 2021

Tags

Information and teaching materials

Infrared

High density polyethylene PE-HD

Sewage sludge

Municipality

Communication strategy

Combined sewar overflows

Prevention of plastics

Polyamide (PA)

Polyester

Polyethylene (PE)

Polyvinyl chloride (PVC)

sampling

Sample purification

Pyrolysis GC

Environmental sustainability

Scanning electron microscopy

Plasticiser

Project sheet

18_Projektblatt_PLAWES_ENG_2018.pdf

Koordinator label

German Federal Institute of Hydrology (BfG) / BfG

MicBin

KALEH — Wed, 20 Dec 2017 09:13:16 +0000

MicBin KALEH Wed, 12/20/2017 - 10:13

Microplastics in Inland Waters – Investigation and Modeling of Entries and Whereabouts in the Danube Area as a Basis for Action Planning

Within the framework of this project, a first-ever accounting of macro-, meso- and microplastics released into the German part of the Danube river basin was achieved, with measuring stations at its main tributaries. Microplastic particles (particles < 5 mm) were examined by using various, complementary analytical methods. The focus lay on specifically small particles that are invisible to the naked eye with diameters less than 300 μm as there is currently a distinct lack of data about these particles. This project mapped the sources, sinks, transport processes and fragmentation of plastics in separate material flow models for micro- and macroplastics. Targeted, standardised sampling and supplementary laboratory experiments are clarifying the relevance of previously neglected input paths such as agricultural land or atmospheric deposition. Results were implemented into existing models, the models were validated and a plastic balance for the German Danube watershed was prepared. Through scenario analyses, it was possible to identify measures to reduce plastic pollution at the level of entire river basins.

Main areas of work

Entry balancing of macro-, meso- and particularly microplastic in the German Danube river basin through uniform sampling campaigns, modelling and supplementary laboratory tests
Balancing of previously unconsidered sources and sinks, such as the input of plastic by agriculture, atmospheric deposition of microplastic and degradation processes of plastics in the environment
Derivation of minimisation strategies

Arbeitspakete

Work packages

WP 1 Coordination

Contact person
Dr. Nicole Zumbülte, TZW: DVGW Water Technology Centre, Analysis and Water Quality department, Karlsruher Straße 84, 76139 Karlsruhe, e-mail: nicole.zumbuelte@tzw.de

Project partner

UOS, UniA, BfG, THK, LfU, BKV

Short description
The TZW was responsible for the scientific and general internal coordination within the project, ensured the exchange of information between the internal and external partners and research networks. This included the organisation of sampling campaigns and sample distribution to the individual partners, the coordination of sample analysis, the organisation of project meetings for exchange between the partners and the maintenance of scientific exchange with other projects at national and international levels.

WP 2 Analysis of plastics in environmental samples

Contact person
Prof. Dr. Thomas Ternes, German Federal Institute of Hydrology (BfG), Am Mainzer Tor 1, 56068 Koblenz, e-mail: ternes@bafg.de

Project partner
LfU, TZW, UOS

Short description
In this work package, the samples from WP 3 and WP 4 were analysed using three complementary methods. Starting from a high sample volume, these were pre-selected in advance by BfG using an effective screening procedure (low sample preparation effort, sample analysis using pyrolysis gas chromatography coupled with mass spectrometry). Samples with contents above a threshold value to be defined were subjected to a much more complex and precise analysis using Raman (TZW) and IR spectroscopy (LfU). These processes provided detailed information on particle properties (concentration, size, polymer type, and shape).

WP 3 Identification of entries / sources

Contact person
Dr. Korbinian Freier, Bavarian State Office for the Environment, Demollstr. 31, 82407 Wielenbach, e-mail: korbinian.freier@lfu.bayern.de

Project partner
THK, BKV, UOS

Short description
The first step in mass balancing of the selective and diffuse input of microplastics requires a characterisation of all potential sources. The aim of WP 3 was therefore to investigate and quantify entries from points and areas in limnic systems. The results were incorporated in WP 5. The focus was on atmospheric deposition, linear inputs in connection with littering, wastewater treatment plants, landfill leachates, and the weathering of plastics.

WP 4 Transport, distribution and fate: Process understanding of water, soil, air

Contact person
Prof. Dr. Thomas Ternes, German Federal Institute of Hydrology (BfG), Am Mainzer Tor 1, 56068 Koblenz, e-mail: ternes@bafg.de

Project partner
BKV, LfU, UniA, TZW, UOS, THK

Short description
In addition to sinks such as hydroelectric power plants, this WP looked at transport and relocation processes of microplastics and possible intermediate reservoirs for microplastics such as soils or water sections with low flow. In addition, degradation and comminution processes of plastics were investigated in laboratory experiments. Sinks or reservoirs for microplastics were identified by coordinated sampling in the water body and mass balancing of a water body section. The results of WP 4 were incorporated into the models of WP 5.

WP 5 Drawing up balance sheets by modelling and deriving measures

Contact person
Dr. Jörg Klasmeier, Osnabrück University, Institute of Environmental Systems Research, Barbarastraße 12, 49078 Osnabrück, e-mail: jklasmei@uos.de

Project partner
LfU, UniA, BKV, TZW

Short description
Entries in water bodies were accounted for considering the various sources and sinks and allowing for an estimation of the total freight in the Danube River System. Process-oriented small to medium scale models for microplastic (UniA, UOS) and supraregional models for micro-, meso- and macroplastic (BKV) were fed with the experimental data and existing data on wastewater treatment plants (LfU, UOS) obtained in the various work packages. From the results of all work packages, a summary evaluation of the sources and sinks with recommendations for measures to reduce water pollution was carried out.

WP 6 Communication

Contact person
Dr. Nicole Zumbülte, TZW: DVGW Water Technology Centre, Analysis and Water Quality Department, Karlsruher Straße 84, 76139 Karlsruhe, e-mail: nicole.zumbuelte@tzw.de

Project partner
LfU, THK

Short description
The MicBin project homepage informs about project contents, actions and results. In addition, a short film was produced and made available to the public. The public was made aware of this issue through a waste collection campaign on the water and participation in the German Sustainability Action Days (DAN). Stakeholders from research, authorities and industry was informed and involved in workshops.

Case Studies

The MicBin project focused on balancing the input of macro-, meso- and particularly microplastics for the German Danube river basin with measurement campaigns at the main Danube tributaries. Among other things, agricultural entries as well as transport and relocation processes were also taken into account.

Coordinator

Dr. Nicole Zumbülte
DVGW Deutscher Verein des Gasund Wasserfaches e. V. – Technischwissenschaftlicher Verein – Bonn
TZW: DVGW-Water Technology Centre, Analysis and Water Quality Department
Karlsruher Straße 84
76139 Karlsruhe
Phone: +49 721-9678 139
e-mail: nicole.zumbuelte@tzw.de

Website

https://www.micbin.de/

Partner Institutions

DVGW-Technologiezentrum Wasser / TZW

Cologne Technical University, STEPs / THK

BKV GmbH / BKV

Bavarian State Office for the Environment / LfU

University of Augsburg / UniA

Osnabrück University / UOS

Duration Period

October 2017

March 2021

Tags

Microplastics

Catchment area

Modeling

minimization strategies

17_Projektblatt_MicBin_ENG_2018.pdf

Project sheet

Koordinator label

https://www.uni-muenster.de/Mikroplatas/en/index.html

MikroPlaTaS

KALEH — Wed, 20 Dec 2017 08:53:43 +0000

MikroPlaTas KALEH Wed, 12/20/2017 - 09:53

Microplastics in Dams and Reservoirs: Sedimentation, Spread, Effects

The spread of microplastics in rivers showed that along a given waterway there are sources as well as sinks. Thus, dams and reservoirs constitute important but until now hardly investigated parts of a water system that serve as examples for risk vs. usefulness of sedimentation of microplastics. Biofilms, which grow on microplastics, have a special significance for their transport and sedimentation. The goals of this project were (I) to identify and characterise microplastic in water and sediment, (II) to understand how biofilms form on plastic and how sedimentation occurs on these grown-over particles, (III) to record how microplastics affect and are taken up by individual organisms as well as by entire communities in model ecosystems, and (IV) to synthesise the scientific results and draft practical recommendations based on them. This synthesis emphasised identifying pathways to eliminate microplastics and to derive practical measures and risk assessments together with the project partners.

Main areas of work

Distribution and sedimentation of microplastics and fauna in situ
Characterisation of microplastics with regard to biofilm communities and sedimentation mechanisms
Direct effects of microplastic on invertebrate species and complex biocenoses
Influence of plastics on the food quality of biofilms for Grazer

Arbeitspakete

Work packages

WP 1 Survey plastics and meio- and microfauna in dams and reservoirs

Contact person
PD Dr. Katrin Wendt-Potthoff, UFZ, Department of Lake Research, Brückstraße 3a, 39114 Magdeburg, e-mail: katrin.wendt-potthoff@ufz.de

Project partner
WWU, Bielefeld University

Short description
The aim was to estimate the contamination of various dammed waters with microplastics, to identify the relevant polymers and to determine the respective typical macro- and meiofauna. Different service water reservoirs (e.g. Bautzen in Saxony) as well as the dammed Ems, the Lippe and the former Rieselfelder Münster in North Rhine-Westphalia were adhesively investigated.

WP 2 In situ experiments on sedimentation rates and settlement

Contact person
PD Dr. Katrin Wendt-Potthoff, UFZ, Department of Lake Research, Brückstraße 3a, 39114 Magdeburg, e-mail: katrin.wendt-potthoff@ufz.de

Project partner
WWU, Bielefeld University

Short description
The aim was to determine field sedimentation rates in the course of a year with regard to total mass and microplastics. For this purpose, sediment traps were applied to the deepest points of the waters, at minimum, and evaluated monthly with regard to the total mass of plastics and organisms of the meiofauna. As a result, a relationship is established between plastic load in the water column, total sedimentation rate and plastic sedimentation rate.

WP 3 Characterisation of biofilms on different polymers

Contact person
Prof. Dr. Bodo Philipp, University of Münster, Institute of Molecular Microbiology and Biotechnology, Corrensstraße 3, 48149 Münster, e-mail: bodo.philipp@uni-muenster.de

Project partner
UFZ, UP, Bielefeld University

Short description
In this work package, the microbial communities on plastic particles were examined with regard to taxonomic composition and function in order to derive hypotheses on processes at the sites that can be checked in WPs 4 – 6. Particular attention was paid to whether there is a characteristic microflora on microplastic particles and whether individual types of plastic differ. Furthermore, mechanisms of biofilm formation on microplastic particles were explained. Cultivation-dependent and -independent investigations were carried out with samples from WP 1 and WP 2 and later with mesocosmic samples (WP 5). A collection of strains is to be generated in the first project year so that it can be used for WP 5 and WP 6.

WP 4 Influence of biofilm colonisation, light and redox processes on microplastic sedimentation

Contact person
PD Dr. Katrin Wendt-Potthoff, UFZ, Department of Lake Research, Brückstraße 3a, 39114 Magdeburg, e-mail:katrin.wendt-potthoff@ufz.de

Project partner
WWU, Bielefeld University

Short description
Experiments under controlled conditions determined how light and redox ratios (concentration of O2 and iron) influence the sedimentation of plastic particles either directly or by controlling colonisation. The influence of these factors on sedimentation was studied to simulate the transition from pelagic to benthic habitat. To what extent light or darkness and oxic or anoxic conditions per se, but also their change, can control the sinking behaviour of plastic particles was determined.

WP 5 Direct effect of plastic particles on invertebrates

Contact person
Prof. Dr. Walter Traunspurger, Bielefeld University, Department of Animal Ecology, Konsequenz 45, 33615 Bielefeld, e-mail: traunspurger@uni-bielefeld.de

Project partner
WWU, UP, Ecossa, Mesocosm

Short description
The uptake and effect of microplastics for aquatic organisms was tested in experimental systems (single-species to model ecosystems) to assess risks for pelagic and benthic fauna. A harmful effect in the organism requires an uptake into the body, either through the ingestion of the particles themselves or through transfer in the food chain (biomagnification). In case of harmful effects, indirect effects (top-down, bottom-up) can occur and thus affect organisms not directly affected by microplastic. In order to evaluate the food web as fully as possible, experiments with increasing ecological complexity and relevance were carried out for pelagic and benthic invertebrates to elucidate the effect on organisms, populations and communities and to reduce the interpretation gap between laboratory and field results.

WP 6 Influence of plastics on the food quality of biofilm for meio and macro grazers

Contact person
Dr. Friederike Gabel, University of Münster, Institute of Landscape Ecology, Heisenbergstraße 2, 48149 Münster, e-mail: gabelf@uni-muenster.de

Project partner
UP, Bielefeld University, UFZ

Short description
The aim of this WP was to identify indirect effects of microplastic on meio and macrofauna organisms by influencing the nutritional basis. Biofilms (especially bacteria, fungi, protozoa) form an important food basis for meio and macrofauna in waters. The quality of these biofilms can therefore have a significant influence on the composition and vitality of the organisms grazing them. For grazing experiments, macro invertebrates were offered different overgrown plastic strips for grazing. Ingestion and excretion rates, growth and, in the case of snails, the reproduction of organisms were investigated.

WP 7 Coordination, public relations, knowledge transfer

Contact person
Dr. Friederike Gabel, University of Münster, Institute of Landscape Ecology, Heisenbergstraße 2, 48149 Münster, e-mail: gabelf@uni-muenster.de

PD Dr. Katrin Wendt-Potthoff, UFZ, Department of Lake Research, Brückstraße 3a, 39114 Magdeburg, e-mail: katrin.wendt-potthoff@ufz.de

Project partner

UP, Bielefeld University, Ecossa, Mesocosm

Short description
The aim was to communicate project results to specific target groups both within the consortium and to the general public (children, students, authorities and scientists). The practical partners (The State Reservoir Administration of Saxony, Lower Water and Landscape Authority of the City of Hamm, Academy of nature and Environmental Protection NRW) played an important role here. The multiplier effect of the addressed target groups promoted the project results and the topic of plastics in the environment and this sensitisation created a broader acceptance for the recommendations for action that arose from the research focus.

Coordinator

PD Dr. Katrin Wendt-Potthoff
Helmholtz Centre for Environmental Research – UFZ,
Department of Lake Research
Brückstraße 3a
39114 Magdeburg
Phone: +49 391 8109810
e-mail: katrin.wendt-potthoff@ufz.de

Website

Partner Institutions

University of Münster / WWU

University of Potsdam / UP

Bielefeld University

Ecossa

Institute for Water Protection Mesocosm GmbH

Duration Period

January 2018

September 2021

Tags

Information and teaching materials

16_Projektblatt_MicroPlaTas_ENG_2018.pdf

Polyvinyl chloride (PVC)

Project sheet

Koordinator label

http://www.emistop.de/page8.html

EmiStop

KALEH — Tue, 19 Dec 2017 16:41:32 +0000

EmiStop KALEH Tue, 12/19/2017 - 17:41

Identification of Industrial Plastic Emissions by Means of Innovative Detection Methods and Technology Development to Prevent the Input into the Environment via the Wastewater Pathway

This project systematically detected emissions of plastics into wastewater from relevant industries. Emissions levels were analysed along all points of the value chain (production, transport, processing, and cleaning of synthetic materials).

The goal was to select wastewater treatment technologies that optimise the reduction of emissions of plastics for the respective value chain. The project evaluated existing technologies for separating particles, investigated deposition rates, and developed approaches for technical optimisation. Optimisation also includes technological developments such as flocculants. Researchers conducted tests in both laboratory and pilot project settings – selected large scale technical wastewater treatment plants were investigated at industrial facilities.

Due to the existing analytical uncertainties, the following detection methods were used to evaluate the existing and developed technologies:

Dynamic differential calometry for qualification and quantification (concentrations)
Raman spectroscopy for qualification and quantification (particle numbers)
Correlations of the plastic concentrations to routine water chemical analyses (for a retrospective estimation of the plastic loads)
Tracer test with magnetic plastic particles (simple and reliable quantification in large dilutions) for balancing in laboratory and pilot tests

Apart from the technical aspects, the focus of this project was also on socio-economic aspects. Thus, measures to prevent economic losses and retain value were reviewed together with the associated industrial enterprises and evaluated with partners from the scientific community and other interest groups.

Main areas of work

Standardisation of sampling and sample preparation for industrial wastewater (in alignment with Plastik-Net and other joint research projects)
Quantitative and qualitative measurement of plastic concentrations in industrial wastewater using Raman spectroscopy and dynamic differential calorimetry
Extended data collection at the sampled industrial waste water treatment plants for the derivation of the plastic loads and testing of a correlation between the measurement results and routine water chemical analyses
Development of magnetic plastic particles in the micrometre range with the physical properties of relevant types of plastic
Development of a tracer test with magnetic plastic particles
Assessment of technologies for particle separation with regard to the retention of (micro-) plastic particles
Optimisation of particle separation technologies
Development of flocculants for the targeted improvement of the retention of individual types of plastics and their mixtures
Delphi surveys of industry and sector associations as well as of politics and science to identify perceived risks and obstacles as well as opportunities and the willingness to participate
Multi-criteria analysis for the development of weighted, ecological and socio-economic criteria for the sustainability assessment of the project results

Arbeitspakete

Work packages

WP 1 Development of analytical methods for plastic particles

Contact persons
Prof. Dr. Jutta Kerpen, RheinMain University, Institute for Environmental and Process Engineering, Department of Wastewater Treatment, Am Brückweg 26, 65428 Rüsselsheim, e-mail: jutta.kerpen@hs-rm.de

Prof. Dr. Susanne Lackner, Technical University of Darmstadt, Institute IWAR, Department of Wastewater Engineering, Franziska-Braun-Straße 7, 64287 Darmstadt, e-mail: s.lackner@iwar.tu-darmstadt.de

Prof. Dr.-Ing. Markus Engelhart, Technical University of Darmstadt, Institute IWAR, Department of Wastewater Technology, Franziska-Braun-Straße 7, 64287 Darmstadt, e-mail: m.engelhart@iwar.tudarmstadt.de

Project partner
EnviroChemie

Short description
A routinely applicable sampling and sample preparation procedure were developed in order to create a uniform and comparable database for industrial wastewater. For the subsequent qualification and quantification of microplastics in (industrial) wastewater samples, the methods of dynamic differential calorimetry and Raman spectroscopy were adapted to industrial wastewater. The respective analysis results were compared with standardised routine measurements and operational self-analysis to determine correlations.

WP 2 Tracer test

Contact persons
Prof. Dr. Susanne Lackner, Technical University of Darmstadt, Institute IWAR, Department of Wastewater Engineering, Franziska-Braun-Straße 7, 64287 Darmstadt, e-mail: s.lackner@iwar.tu-darmstadt.de

Dr. Kyriakos Eslahian, BS-Partikel GmbH, Nestléstr. 41, 55120 Mainz, e-mail: eslahian@bs-partikel.de

Short description
In order to balance individual process technologies for plastic particle retention in real water matrices, a method for the quantification of magnetic plastic particles by means of magnetic susceptibility scales was established. For this purpose, particles in the size range from 1 μm to 300 μm were synthesised with the greatest possible magnetic susceptibility, which imitate the morphologies and chemical properties of environmental plastic particles.

Furthermore, a continuous method for the production of these particles was established in order to ensure the best possible reproducibility and scalability for subsequent applications.

WP 3 Identification of industrial entry points

Prof. Dr. Susanne Lackner, Technical University of Darmstadt, Institute IWAR, Department of Wastewater Engineering, Franziska-Braun-Straße 7, 64287 Darmstadt, e-mail: s.lackner@iwar.tu-darmstadt.de

Project partner
EnviroChemie, inter 3

Short description
The entry points of microplastics from industrial wastewater into surface waters were determined by uniform characterisation and quantification of the plastic emissions of individual industrial plants. The evaluation of plastic emissions on the basis of mass flows, variations and production information with key figure system and balance tools, hotspots and temporal variations of the particle input were identified.

WP 4 Balancing of technical systems

Contact persons

Dr.-Ing. Eva Bitter, EnviroChemie GmbH, F&E, In den Leppsteinswiesen 9, 64380 Rossdorf, e-mail: eva.bitter@envirochemie.com

Project partner

TU-AW, inter3, HSRM

Short description
In laboratory and pilot tests, various process techniques (filtration in various filter units such as membrane plants, double-layer filters, cloth filters; flocculation in combination with filtration, flotation or sedimentation) were evaluated with regard to plastic particle removal. For this purpose, the tracer particles developed in WP 2 were used, which enable the use of synthetic and real industrial waste water. Furthermore, the existing industrial process technology was evaluated at different industrial sites and optimised with regard to the separation of plastic particles.

WP 5 Optimisation of plastic retention

Contact persons
Dr.-Ing. Eva Bitter, EnviroChemie GmbH, F&E, In den Leppsteinswiesen 9, 64380 Rossdorf, e-mail: eva.bitter@envirochemie.com

Project partner
TU-AW

Short description
Based on the results of WP 4, the pilot plants were adapted by specific design changes (e.g. flow control, sludge removal, conveyor technology) and the success of these optimisations was evaluated in further balancing experiments. For the industries considered, in addition to constructive optimisation of process engineering, production-integrated measures to reduce plastic emissions were derived. The production information collected in WP 3 served as the basis for this.

WP 6 Development of flocculants for plastics sorts

Contact persons
Dr.-Ing. Eva Bitter, EnviroChemie GmbH, F&E, In den Leppsteinswiesen 9, 64380 Rossdorf, e-mail: eva.bitter@envirochemie.com

Project partner
TU-AT, TU-AW

Short description
In experiments with beakers, individual polymers for the targeted flocculation of particles of different types of plastic in the size range from 10 to 300 μm were tested. The results were then used to test specific blends of polymers to produce the most stable flakes of particles of individual plastic types. With these results, the tests and developments were extended to mixtures of different types of plastics.

The laboratory test results were then supplemented by pilot tests using tracer particles developed in WP 2.

WP 7 Risk and potential analysis

Contact person
Dipl.-Ing. Wolf Raber, inter 3 GmbH - Institute for Resource Management, Otto-Suhr-Allee 59, 10585 Berlin, e-mail: raber@inter3.de

Project partner
TU-AT, TU-AW, EnviroChemie, HSRM, BS-Partikel

Short description
To maximise the broad application of the EmiStop optimisation approaches and avoidance strategies, the risks and potentials were identified from the perspective of the key actors, evaluated and fed into the project at an early degree of technology maturity. Furthermore, an expert-supported set of sociopolitical, economic, and ecological evaluation criteria and a meaningful set of indicators were derived in order to analyse and evaluate the multicriterial optimisation approaches and avoidance strategies and in a next step measures for implementation and diffusion.

WP 8 Management and communication

Contact persons
Dr.-Ing. Eva Bitter, EnviroChemie GmbH, F&E, In den Leppsteinswiesen 9, 64380 Rossdorf, e-mail: eva.bitter@envirochemie.com Dr. Anja Steglich, inter 3 GmbH - Institute for Resource Management, 10585 Berlin, e-mail: steglich@inter3.de

Project partner
TU-AT, TU-AW, HSRM, BS-Partikel

Short description
In order to disseminate and implement the project results, industrial companies were actively involved and dialogue is carried out with experts from relevant industry associations (e.g. PlasticsEurope e.V., IK Industrievereinigung Plastikverpackungen e.V., GKV Gesamtverband Plastikverarbeitende Industrie e.V.). The collaboration was commissioned to a) develop the results into a consensual overall perspective, b) prepare these into action-oriented and implementable guidelines and c) make them available via established channels and multipliers, e.g. the Responsible Care Initiative of the chemical industry.

Coordinator

Dr.-Ing. Eva Bitter
EnviroChemie GmbH
In den Leppsteinswiesen 9
64380 Rossdorf
Phone: +49 6154-6998-57
e-mail: eva.bitter@envirochemie.com

Website

Partner Institutions

Technical University of Darmstadt, Institute IWAR, Department of Wastewater Engineering

Technical University of Darmstadt, Institute IWAR, Department of Wastewater Technology

RheinMain University, Institute for Environmental and Process Engineering / HSRM

inter 3 GmbH-Institute for Resource Management

BS-Partikel GmbH

Duration Period

January 2018

December 2020

Tags

Environmental accounting

15_Projektblatt_EmiStop_ENG_2018.pdf

Polymer analysis

Polypropylene (PP)

Polystyrene (PS)

Polyvinyl chloride (PVC)

Project sheet

Koordinator label

https://www.wasser.tum.de/en/ submuetrack/startseite/

SubμTrack

KALEH — Tue, 19 Dec 2017 15:21:00 +0000

SubμTrack KALEH Tue, 12/19/2017 - 16:21

Tracking of (Sub)Microplastics of Different Identities - Innovative Analysis Tools for Toxicological and Process-engineering Evaluation

The methods currently available for the analysis of microplastics in environmental matrices were primarily designed for particles in the size range of 1 μm to 5 mm. Smaller particles below 1 μm were hardly detected. However in contrast to larger particles, these are able to enter cells and have a higher potential for adsorption of pollutants due to their relatively larger surface. SubμTrack focuses on plastic particles between 50 nm and 100 μm, because of their higher ecotoxicological relevance. For this purpose, the previously available detection range was extended and new methods for sampling, sample preparation, and analysis were developed. Another focus of the project were the possible effects of submicroplastic particles on the aquatic environment and on human health. The results of these studies were complemented by an assessment of the social, political and legal dimensions of plastic emission into the environment. By analysing the perception of the problem and possible strategies for action, foundations were laid for active processes of social change. The results were also examined regarding to their implementation in legislation, standardisation, and their relevance for voluntary actions.

Main areas of work

Characterisation of particles and comparison with reference materials
Impact on the aquatic environment and human health
Social, political and legal dimensions of plastic emission into the environment

Arbeitspakete

Work packages

WP 0 Organisation, coordination and public relations

Contact persons
Prof. Dr.-Ing. Jörg E. Drewes, Technical University of Munich, Chair of Urban Water Systems Engineering, Am Coulombwall 3, 85748 Garching, e-mail: j.drewes@tum.de

Project partner
TUM-IWC, TUM-LTI, TUM-LAS, TUM-MCTS, IGOE, LfU, UBA, IUTA, Postnova Analytics GmbH, BS-Partikel GmbH

Short description
In addition to the coordination of results and products within the consortium, WP 0 also included the coordination of activities with partners outside the project. The goal was the sustainable implementation of the analytical techniques, the results and the instructions for action of harmonised strategies in close cooperation with national and international key institutions. The public relations work was mainly coordinated by TUM-SWW and effectively implemented by partners of different orientations.

WP 1 Selection and production of reference particles

Contact persons
Dr. Carmen Nickel, Dr. Jochen Türk, Institute of Energy and Environmental Technology e. V. (IUTA), Bliersheimer Str. 58- 60, 47229 Duisburg, e-mail: nickel@iuta.de; tuerk@iuta.de

Project partner
LfU, BS-Partikel GmbH

Short description
Together with the partners of BS-Partikel and the leaders of the experimental WPs 2 – 5 the required reference particles were identified. In particular, the size, material, marking and the availability of the particles played an important role. The reference particles were selected during the initial phase of the project in order to have enough time to fabricate or purchase the particles at the beginning of the experiments. The project partners BS-Partikel and IUTA then provided the corresponding particles.

WP 2 Comprehensive analysis of microplastic particles

Contact persons
Prof. Dr. Martin Elsner, Dr. Natalia P. Ivleva, Technical University of Munich, Chair of Analytical Chemistry and Water Chemistry, Institute of Hydrochemistry, Marchionistrasse 17, 81377 Munich, e-mail: natalia.ivleva@ch.tum.de

Project partner
Postnova Analytics GmbH, BS-Partikel GmbH, TUMSWW, TUM-LTI, LfU, IUTA

Short description
Innovative and proven analytical detection methods (including sampling, preparation, identification and quantification) for microplastics (1 μm – 5 mm) were determined and tested with reference materials in the submicron range. The most successful techniques of the MiWa project running since 2016 serve as a starting point for this; standard methods from this project were integrated and compared. Direct contact to actors of the MiWa project was guaranteed by partners of the consortium (TUM-IWC and UBA).

WP 3 Studies on aging, adsorption and desorption of organic trace substances on reference particles

Contact persons
Prof. Dr.-Ing. Jörg E. Drewes, Technische Universität München, Lehrstuhl für Siedlungswasserwirtschaft, Am Coulombwall 3, 85748 Garching, e-mail: j.drewes@tum.de

Project partner
LfU

Short description
The particles used in the method validation are subjected to systematic aging processes and biofilm growth. Furthermore, these particles and especially their (resulting) different surfaces were examined regarding their adsorption or desorption characteristics of organic molecules. For this analysis, adsorption and desorption kinetics, among other things, were investigated. This was done by applying TD-(Pyrolysis)-GC-MS and LC-MS/MS. Experiments with the aged particles were carried out in so-called batch approaches, but also in laboratory wastewater treatment plants operated at the LfU. All samples were also stored in the biological systems of WP 5 if required.

WP 4 Investigations on entry points and process-related evaluation

Contact person
Dr. Korbinian Freier, Bavarian State Office for the Environment, Demollstraße 31, 82407 Wielenbach, e-mail:korbinian.freier@lfu.bayern.de

Project partner
TUM-SWW, IUTA

Short description
Using the methods developed and validated in WP 2, real scenarios were first simulated with reference particles in laboratory wastewater treatment plants at the partner LfU to analyse the fate of the particles within the system. Parallel to this, investigations were carried out at various measuring points in real wastewater treatment plants. Water samples were certified by IUTA for micropollutants. The aim was to extend the existing sampling technologies to micropollutants. Finally, together with the other partners of the project and based on the expected results, a process-related evaluation was carried out.

WP 5 Impact on aquatic environment and human health

Contact person
Prof. Dr. Michael Pfaffl, Technical University of Munich, TUM School of Life Sciences Weihenstephan, Technical University of Munich, Chair of Animal Physiology and Immunology, Weihenstephaner Berg 3, 85354 Freising, e-mail: michael.pfaffl@wzw.tum.de

Project partner
TAM-LAS, IGOE

Short description
Potential negative effects of submicroparticles on different biological organisational levels were investigated and compared to obtain a comprehensive ecotoxicological evaluation. This includes the use of model systems in vivo to determine effects on microbial diversity, communities and trophic structures and functions as well as to identify stress reactions on a higher organismic level. In vitro models extended this approach for the determination of effects on the cellular and molecular level. Based on this a mechanistic understanding of particle-induced stress reactions was created and potential effects on human health were derived.

WP 6 Social, political and legal dimensions

Contact person
Prof. Dr. Ruth Müller, Technical University of Munich, Assistant Professorship of Science and Technology Policy, Augustenstraße 46, 80333 Munich, e-mail: ruth.mueller@tum.de

Project partner
UBA

Short description
At TUM-MCTS current problem perceptions and coping strategies in society and politics with regard to plastic particles in the environment were analysed by means of qualitative social scientific methods. The focus lay on the perception of the specific ecotoxicological relevance of submicroparticles. UBA carried out a screening of the relevant legal acts at national, European and intercontinental levels. The consideration goes beyond the pure media reference (water, soil and air) and the associated possible transport paths. In particular, the legally undefined range between nano- (limit: 100 nm) and microplastics (frequently stated limit: 1 μm) is of primary interest.

Coordinator

Prof. Dr.-Ing. Jörg E. Drewes
Technical University of Munich,
Chair of Urban Water Systems Engineering / TUM-SWW
Am Coulombwall 3
85748 Garching
Phone: +49 89 2891 3701 bzw. -3718
e-mail: jdrewes@tum.de

Website

Partner Institutions

Technical University of Munich

Institute of Hydrochemistry, Chair of Analytical Chemistry and Water Chemistry / TUM-IWC

Chair of Animal Physiology and Immunology/ TUM-LTI

Chair of Aquatic Systems Biology / TUM-LAS

Assistant Professorship of Science and Technology Policy / TUM-MCTS

Helmholtz Centre Munich, Institute of Groundwater Ecology / IGOE

Bavarian State Office for the Environment / LfU

Federal Environmental Agency / UBA

Institute of Energy and Environmental Technology e. V. / IUTA

Postnova Analytics GmbH

BS-Partikel GmbH

Duration Period

September 2017

June 2021

Tags

Adsorption

in vitro test systems

Scanning electron microscopy

Nano plastics

Field flow fractionation

Project sheet

09_Projektblatt_SubµTrack_ENG_2018.pdf

Koordinator label